中空纳米球Co3O4/NiO复合材料的制备及其储锂性能

李志桐1, 李佳双1,2*, 江文雪3, 聂家琎1, 赵健1, 姚少巍1,2

化工新型材料 ›› 2021, Vol. 49 ›› Issue (10) : 87 -91.

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化工新型材料 ›› 2021, Vol. 49 ›› Issue (10) : 87-91. DOI: 10.19817/j.cnki.issn 1006-3536.2021.10.018
新材料与新技术

中空纳米球Co3O4/NiO复合材料的制备及其储锂性能

    李志桐1, 李佳双1,2*, 江文雪3, 聂家琎1, 赵健1, 姚少巍1,2
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Preparation and lithium storage property of Co3O4/NiO hollow nanosphere

  • Li Zhitong1, Li Jiashuang1,2, Jiang Wenxue3, Nie Jiajin1, Zhao Jian1, Yao Shaowei1,2
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摘要

利用水热法制备了碳球,以碳球为模板合成出NiO和Co3O4/NiO纳米球状负极材料,对其储锂性能进行对比分析。通过X-射线衍射(XRD)、场发射扫描电子显微镜(FESEM)、热重(TG)、氮气等温吸脱附(BET)、蓝电测试系统及电化学工作站对两种材料分别进行表征和分析。结果显示,当电流密度为100mA/g时,Co3O4/NiO负极材料的首次放电比容量为1142mAh/g,循环100次后放电比容量仍稳定在770mAh/g,库伦效率接近100%。证明Co3O4/NiO电极材料具有良好的电化学性能,有望应用在锂离子电池负极材料中。

Abstract

Carbon spheres were prepared by hydrothermal method,and anode materials of NiO and Co3O4/NiO nanospheres were synthesized by using carbon spheres as templates,and compared and analyzed their electrochemical properties.The both materials were characterized and analyzed by X-ray diffraction (XRD),scanning electron microscopy (SEM),thermogravimetric analysis (TGA),Brunner-Emmet-Teller (BET) and LAND test system and electrochemical workstation,respectively.The results showed that when the current density was 100mA·g-1,the first discharge specific capacity of the Co3O4/NiO anode material was 1142mA·h·g-1,and the specific discharge capacity remained stable at about 770mA·h·g-1 after 100 cycles,and the columbic efficiency was close to 100%.The results shown that the Co3O4/NiO had good electrochemical properties,and expected to be used in the anode materials of lithium ion battery.

关键词

氧化镍 / 四氧化三钴/氧化镍 / 电化学性能 / 锂离子电池 / 负极材料

Key words

NiO / Co3O4/NiO / electrochemical property / lithium ion battery / anode material

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中空纳米球Co3O4/NiO复合材料的制备及其储锂性能[J]. 化工新型材料, 2021, 49(10): 87-91 DOI:10.19817/j.cnki.issn 1006-3536.2021.10.018

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基金资助

唐山市工业废气高效脱硫脱硝基础创新团队(17130201D)

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